Add coffee, brown sugar, Worcestershire sauce, Italian seasonings, paprika, garlic and salt to a small saucepan.
Bring to a boil, lower to simmer and cook 5 minutes.
Set aside to cool or place in freezer for about 15 minutes.
Add chicken to a bowl and pour marinade over the top. Stir well until evenly coated. Cover and refrigerate at least one hour our up to 12 hours.
To Grill chicken: Prepare grill to a 300° fire with hickory or oak for smoke flavor.
Place chicken over fire and cook 2 minutes, turn to sear the other side about 2 minutes.
Move chicken to indirect heat and cook for 12-15 minutes or until internal temperature reaches 165°.
Add pineapple to indirect heat for 5-7 minutes, turning once just until pineapple starts to caramelize.
Allow chicken to rest 5 minutes before serving.
Serve chicken with grilled pineapple.